... sodium;azide . Avoid contact with acids or heavy metals. ... James O. 26628-22-8 Revision Date 2007-07-01 : Sodium azide Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). 5.2. Chemical Safety: Sodium Azide Hazards January 11, 2010 | APPEARED IN VOLUME 88, ISSUE 2 ADVERTISEMENT. Sodium Azide must never be drain disposed, due to build-up of metal azides in metal plumbing lines and the toxicity to aquatic life. 100. Even dilute solutions of sodium azide must not be poured down the ⦠LINK: International Chemical Safety Card for sodium azide. 302/304/311/312 extremely hazardous substances: Sodium azide SARA 313 toxic chemical notification and release reporting: Sodium azide CERCLA: Hazardous substances. Sodium azide CAS-No. Sodium Azide Sodium Azide (IARC) IMIS: S113 Hydrazoic acid & Azide, Sodium trinitride, Smite, Azium, sodium salt NaN 3 carcinogenic classification: Group 3-not classifiable as to its carcinogenicity to humans CAS 26628-22-8 PUBCHEM N/A EC 247 ⦠Registration dossier . Sodium azide is a metabolic inhibitor that interferes with oxidative enzymes and inhibits phosphorylation. Sodium azide is very toxic to aquatic life and may cause long-term adverse effects in the aquatic environment. Sodium azide Revision Date 25-Apr-2019 Reactive Hazard Yes Stability Risk of explosion by shock, friction, fire or other sources of ignition. In fact, sodium azide is used in airbags for this very reason. Teratogenicity : No known significant effects or critical hazards. View information & documentation regarding Sodium azide, including CAS, MSDS & more. US sodium azide 26628-22-8 REL NIOSH REL US sodium azide 26628-22-8 TLV® ACGIH® 2018 Notation STEL short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-minute period (unless otherwise specified) Safety Data Sheet acc. Boston, MA: Butterworth-Heinemann Ltd., 1990. Accidental mix of bleach and acid kills Buffalo Wild Wings employee; Mutagenicity : No known significant effects or critical hazards. 1687 Proper shipping name SODIUM AZIDE Hazard Class 6.1 Packing Group II 15. Great care must be taken to handle Sodium Azide in a manner that contamination with metals doesnât occur, as the formation of metal azides can present an explosion hazard when formed crystals are left to dry. Additional Information. Sodium azide (NaN 3), a colorless-to-white crystalline solid that is odorless and moderately soluble in water, is the most prevalent inorganic compound used as an antibacterial and antimicrobial agent in bulk reagents and stock solutions in the in vitro diagnostics (IVD) industry.If you were to review the composition of almost any phosphate-buffered saline ⦠SARA 311/312 Hazards: N/A US State Regulations: California Prop. Heat, flames and sparks. If elapsed time since ingestion of sodium azide (Na(N3)) is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step 4. It is often a better choice for this purpose than thimerosal, as sodium azide does not contain mercury. Incompatible Materials Acids, Oxidizing agents, Peroxides, Acid chlorides, Metals Hazardous Decomposition ⦠Preparation Inorganic azides. Physical hazards. Hydrazoic acid, sodium salt . Sodium azide (NaN3) | N3Na | CID 4427778 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. The driver-side airbag can is about 1 and 1/2 inches long and holds about 50 grams of sodium azide. This material does not contain any Class 1 ⦠Sodium azide, used mainly as a preservative in aqueous laboratory reagents and biologic fluids and as a fuel in automobile airbag gas generants, has caused deaths for decades. 6. H400-Very toxic to aquatic life. Risk of fire and explosion on contact with acids or metals. Plumbers can then accidentally detonate these compounds. Hazards and Safety. Sodium azide Sodium azide Classification open all close all. Explosives Reason for no classification: ... hazard class not assessed Oxidising gases Reason for no classification: data conclusive but not sufficient for classification Gases under pressure In one case, sodium azide was poured into a drain, where it exploded and the toxic gas was inhaled (breathed in). Sodium azide â¥99%; CAS Number: 26628-22-8; EC Number: 247-852-1; Linear Formula: N3Na; find Sigma-Aldrich-13412 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. STOT - single exposure None known STOT - repeated exposure Central nervous system (CNS) Cardiovascular system Liver Kidney Heart spleen Aspiration hazard No information available Symptoms / effects,both acute and delayed No information available Sodium Azide (NaN 3) is an inorganic compound commonly used as the gas forming agent in airbag systems.It is both highly toxic and reactive. Toxicological information Not available. Sodium azide Revision Date 25-April-2019 Teratogenicity No information available. Clean Air Act: This material does not contain any hazardous air pollutants. Handbook of Reactive Chemical Hazards 4th ed Bretherick, L. Handbook of Reactive Chemical Hazards. Lori Stiles. Wear, âAzide Hazards with Automatic Blood Cell Counters,â Journal of Chemical Education, 52, A23-A25, January 1975. CHEMICAL INFORMATION SHEET: SODIUM AZIDE, NaN3 SYNONYM(S) Azide, Azium, Sodium salt of hydrazoic acid CAS NUMBER 26628 -22 -8 MOLECULAR WEIGHT 65.02 PHYSICAL HAZARDS: * REACTIVE INCOMPATIBILITIES: When mixed with water or an acid, or comes in contact with a solid metal **it changes rapidly to form a toxic gas with a pungent odor. Hazard classification & labelling Hazard classification and labelling. Its exposure potential for the general population increases as the use of airbags increase. Sodium azide 0.05 Yes 500 - 1,000 - SARA 304 RQ: 2,000,000 lbs / 908,000 kg SARA 313 Components: Sodium azide is subject to reporting requirements of Section 313, Title III of SARA. 26628-22-8 Revision Date 2007 -07 -01 SARA 311/312 Hazards Acute Health Hazard, Chronic Health Hazard Massachusetts Right To Know Components Sodium azide CAS-No. However, sodium azide does have hazards. Sodium azide 26628-22-8 - - - - Chemical Name California Hazardous Waste Status Sodium azide 26628-22-8 Ignitable; Reactive 14. Other Classifications: Sodium azide is highly toxic. I.A.5. Sodium azide is used as a chemical preservative in hospitals and laboratories. Conditions to Avoid Incompatible products. Most Popular in Safety. Gives off irritating or toxic fumes (or gases) in a fire. Sodium azide tablets are stacked like small hockey pucks in two-inch-diameter metal canisters inside airbags. Sodium Azide Hazards and Disposal Sodium azide is used at UNO in the preservation of samples and stock solutions. Carcinogenicity : No known significant effects or critical hazards. Avoid dust formation. hazards should sodium azide come in contact with metals. Sodium azide is a common preservative in many in vitro diagnostic products and is found in concentrations up to 0.1% in diluents used with automatic blood cell counters. Improper disposal down sink drains can cause Sodium Azide to react with Copper and Lead pipes to form highly explosive Lead Azide and Copper Azide. Antibodies with 0.1% Sodium Azide Section 11. 26628-22-8 Revision Date 2007-07-01 Pennsylvania Right To Know Components Sodium azide CAS-No. V. Daniels, S Ward, "A Rapid Test for the Detection of Substance which will Tarnish Silver" Studies in Conservation, 27(2), 1982, p.58-60. A characteristic effect of acute administration of sodium azide to experimental animals is hypotension (Reinhardt and Britelli, 1982). Physical Hazards: Sodium azide can form explosive compounds when it comes into contact with or dries on metal surfaces, this includes metal spatulas or other metal lab equipment. Avoid shock and friction. 1.0% de minimis concentration. Other identifiers . VY8050000: DOT ID & Guide 1687 153: Formula NaN 3: Conversion: IDLH N.D. See: IDLH INDEX : Exposure Limits NIOSH REL 5. Sodium Azide Solutions: Potential Hazards for Explosions from Improper Handling and Disposal, August 5, 2015. Sodium azide is made industrially by the reaction of nitrous oxide, N 2 O with sodium amide in liquid ammonia as solvent:. SODIUM AZIDE: ICSC: 0950: Hydrazoic acid, sodium salt Azide Azium: April 2014: CAS #: 26628-22-8: UN #: 1687 EC Number: 247-852-1 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Combustible. 1687 Proper shipping name SODIUM AZIDE Hazard Class 6.1 Packing Group II IATA UN/ID no. sodium azoimide . Registration dossier . Many inorganic azides can be prepared directly or indirectly from sodium azide. Special Protective Equipment for Firefighters Nitrogen-diluted bromine vapor passed over silver or sodium azide formed bromine azide, and often caused explosions /metal azides/. Heavy-metal azides are notoriously explosive. Sodium Azide Handling. Sodium Azide. TRANSPORT INFORMATION DOT UN/ID no. A vehicle, upon sensing an impact, will send an electrical charge that heats the sodium azide to high temperatures â causing the rapid formation of nitrogen gas. Hazards. Sodium Azide in Car Airbags Poses Growing Environmental Hazard, UA Scientist Says. It is unlikely that a dilute sodium azide solution that ⦠N 2 O + 2 NaNH 2 â NaN 3 + NaOH + NH 3. Specific Hazards Arising from the Substance or Mixture. to 29 CFR 1910.1200 App D 5% (w/v) Sodium Azide Version number: GHS 3.0 Proper personal protective equipment. Ipecac should not be administered to children under 6 months of age. Sigma-Aldrich offers a number of Sodium azide products. 26628-22-8 RTECS No. Sodium azide exposure can result in headache, respiratory distress, and diarrhea. Accidents have occurred in these settings. H410-Very toxic to aquatic life with long lasting effects. 011-004 ⦠Welcome to PubChem! This material contains Sodium azide (CAS# 26628-22-8, 99+%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Avoid disturbing corroded materials if the corrosion may be due to sodium azide. In order for sodium azide to form an explosive lead azide or copper azide it must come into contact with lead, copper and/or their lead/copper salts. Sodium azide ⦠65: No ingredient regulated by CA Prop 65 present. Hazard Statement. Registration dossier . Sodium azide Synonyms & Trade Names Azide, Azium, Sodium salt of hydrazoic acid CAS No. 5.3. Sodium azide is currently undergoing testing for chronic oral toxicity in rats (NTP, 1985). 4th ed. Warning: Ingestion of sodium azide (Na(N3)) may result in sudden onset of seizures or loss of consciousness. Pennsylvania RTK: Sodium azide Massachusetts RTK: Sodium azide TSCA 8(b) inventory: Sodium azide SARA 302/304/311/312 extremely hazardous substances: Sodium azide SARA 313 toxic chemical notification and release reporting: Sodium azide CERCLA: Hazardous substances. General : No known significant effects or critical hazards. Trade names .
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